
Thermal Stability and Melt Processing Rules for Polyhydroxyalkanoate Resins
Polyhydroxyalkanoate processing demands strict moisture control below 200 ppm and residence times under three minutes to prevent cis-elimination chain scission.

Polyhydroxyalkanoate processing demands strict moisture control below 200 ppm and residence times under three minutes to prevent cis-elimination chain scission.

Residual moisture above 50 ppm hydrolyzes rPET melt within seconds, dropping intrinsic viscosity and causing brittle part failure that exceeds drying power costs.

Intrinsic viscosity loss in PET processing is determined by measuring dilute solution flow time or capillary melt viscosity to quantify polymer chain cleavage.

Polyethylene terephthalate ester bonds hydrolyze rapidly in melt above 270 °C, requiring drying below 30 ppm moisture to prevent intrinsic viscosity collapse.
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